We study vacuum alignment in theories in which the chiral symmetry of a set
of massless fermions is both spontaneously and explicitly broken. We find that
transitions occur between different phases of the fermions' CP symmetry as
parameters in their symmetry breaking Hamiltonian are varied. We identify a new
phase that we call pseudoCP-conserving. We observe first and second-order
transitions between the various phases. At a second-order (and possibly
first-order) transition a pseudoGoldstone boson becomes massless as a
consequence of a spontaneous change in the discrete, but not the continuous,
symmetry of the ground state. We relate the masslessness of these ``accidental
Goldstone bosons'' (AGBs) bosons to singularities of the order parameter for
the phase transition. The relative frequency of CP-phase transitions makes it
commonplace for the AGBs to be light, much lighter than their underlying strong
interaction scale. We investigate the AGBs' potential for serving as light
composite Higgs bosons by studying their vacuum expectation values, finding
promising results: AGB vevs are also often much less than their strong scale.Comment: 27 pages, latex, with 12 postscript figure