research

Structural, morphological, ionic conductivity, and thermal properties of pectin-based polymer electrolytes

Abstract

New polymer electrolytes (PEs), potentially interesting for solid-state electrochemical devices applications, were synthesized by a solvent casting method using pectin and ionic liquid (IL) N,N,N-trimethyl-N-(2-hydroxyethyl)ammonium bis(trifluoromethylsulfonyl)imide ([N1 1 1 2(OH)][NTf2]. The resulting electrolytes besides being moderately homogenous and thermally stable below 155 ºC, they also exhibited good mechanical properties. The SPE membranes were analyzed by differential scanning calorimetry (DSC), X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), and complex impedance spectroscopy.This work was supported by FEDER through the COMPETE Program and by Fundação para a Ciência e a Tecnologia (FCT) in the framework of the Strategic Projects PEST-C/QUI/UI0686/2013, grants FCT Investigator contract (J.M.S.S.E.). The authors are also indebted to CNPq (grant 201820/2014-5), FAPESP, and CAPES for the financial support given to this research. M.M. Silva acknowledges CNPq (PVE grant 406617/2013-9) for the mobility grant provided by these institutions. The authors are also acknowledges to Dra. Ivana for AFM data.info:eu-repo/semantics/publishedVersio

    Similar works