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Magnesium and aluminum sulfates in salt efflorescences from acid mine drainage in the Iberian Pyrite Belt (SW Spain)

Abstract

Proceedings IMWA 2016, Freiberg/Germany | Drebenstedt, Carsten, Paul, Michael (eds.) | Mining Meets Water – Conflicts and Solutions.The current study is focused on AMD-precipitates that compose the typical magnesium and aluminum sulfate assemblages in the Spanish sector of the Iberian Pyrite Belt (SW Spain). The main objectives are identify and describe the composition, morphology and paragenetic relationships of these sulfate phases. From the methodological pint of view, sampling procedure covered the entire metallogenetic province, including five selected representative mines and eight river basins, which are the main receptors of the acid mine drainage discharges. The mineralogical analyses were performed by X-Ray diffraction and electron microscopy. The obtained results showed the extraordinary abundance of aluminum sulfates with acicular habit, from the series pickeringite-apjhonite-halotrichite. They form typical assemblages with other aluminum sulfates, such as alunogen and tamarugite, and with the Mg sulfates: epsomite and hexahydrite. Moreover, the paragenetic relationships indicate the late occurrence of acicular Alsulfates from the halotrichite group.Financial support for this research was provided by the Andalusian Autonomous Government Excellence Project, code P06-RNM-02167. This work was also co-funded by the European Union through the European Regional Development Fund, based on COMPETE 2020 (Programa Operacional da Competitividade e Internacionalização), project ICT (UID/GEO/04683/2013) with reference POCI-01-0145-FEDER-007690 and national funds provided by Fundação para a Ciência e Tecnologia.info:eu-repo/semantics/publishedVersio

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