The Eastern Black Sea region of the South Caucasus contains an extremely rich record of metallurgical remains that is poorly known outside of the former Soviet Union. Large numbers of relatively small smelting sites dot the foothill regions, forming a dispersed, yet large-scale metallurgical landscape. New fieldwork in the region has followed up on earlier Soviet period research, relocating and reanalyzing previously known sites and identifying new ones. This paper presents a series of 33 radiocarbon (14C) dates from copper and iron smelting sites in this region. Dates from copper smelting sites suggest that copper smelting occurred over a shorter and more intense period than previously thought, between about 1300 and 800 BC. Dates from newly discovered iron smelting sites place these activities in two episodes during the Classical-Hellenistic period (ca. 500–200 BC) and the High Medieval period (ca. AD 1050–1400). The dramatic expansion in bronze production immediately prior to the adoption of iron mirrors patterns in other regions of Europe and the Near East, and has implications for understanding the economic contexts in which iron emerged. While the new dates from iron smelting sites provide only an initial outline of the iron production chronology in the region, they represent an important step for resolving outstanding issues from previous investigations