We report the first observation of the decay modes B0→D+D−, B−→D0D− and B−→D0D∗− based on 152 × 106BBˉ
events collected at KEKB. The branching fractions of B0→D+D−, B−→D0D− and B−→D0D∗− are found to be (3.21±0.57±0.48)×10−4, (5.62±0.82±0.65)×10−4 and (4.59±0.72±0.56)×10−4, respectively. Charge asymmetries in the B−→D0D− and B−→D0D∗− channels are consistent with zero.Comment: 9 pages, 2 figures, KEK Preprint 2004-99, Belle Prerpint 2005-3,
submitted to PR