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丙二酸二甲酯均相催化加氢合成3-羟基丙酸甲酯的研究
Authors
刘睿
张春燕
+4 more
方霄龙
朱红平
段宁
章敏
Publication date
31 January 2019
Publisher
Abstract
本文以乙酰丙酮钌和膦胺配体作为催化剂体系,用于催化丙二酸二甲酯加氢制3-羟基丙酸甲酯.围绕催化反应性能,系统探讨了配体结构和用量、温度、时间以及溶剂等对丙二酸二甲酯转化率和3-羟基丙酸甲酯产率的影响.研究发现,乙酰丙酮钌和o-二苯基膦苯胺构成的催化剂体系在合适反应条件下可以有效催化丙二酸二甲酯选择性加氢制3-羟基丙酸甲酯.在优化的反应条件下,这一催化剂体系也可以催化多种不同结构酯类分子加氢制醇
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Xiamen University Institutional Repository
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oai:dspace.xmu.edu.cn:2288/176...
Last time updated on 20/11/2020
Xiamen University Institutional Repository
See this paper in CORE
Go to the repository landing page
Download from data provider
oai:dspace.xmu.edu.cn:2288/176...
Last time updated on 20/11/2020