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金属固溶体热膨胀系数的CALPHAD计算模型
Authors
丁琪
刘兴军
+5 more
施展
李晓菲
王翠萍
许伟伟
韩佳甲
Publication date
15 September 2019
Publisher
Abstract
基于计算相图方法(CALPHAD方法),借鉴经典热容模型,通过增加额外的磁性项参数,构建了包含铁磁-顺磁转变的金属固溶体热膨胀系数的CALPHAD计算模型。结合Ni-Fe二元合金的实验结果,采用Levenberg-Marquardt法对模型参数进行了评估,优化得到了300~1200 K范围内Ni-Fe二元金属固溶体热膨胀系数的相互作用参数。采用得到的模型参数,对Ni-Fe二元金属固溶体的热膨胀系数进行了计算,计算结果准确地描述了Ni-Fe二元金属固溶体在居里温度附近的尖锐峰。随着Fe含量的增加,居里温度处的峰值减小,热膨胀曲线由峰状变成谷状,与实验值吻合。该计算模型可以准确计算任意Fe含量<50%(质量分数)的Ni-Fe二元金属固溶体的热膨胀系数。国家重点研发计划项目(2017YFB0701603,2016YFB0701401)福建省自然科学基金项目(2016J01256)国家自然科学基金青年基金项目(51601161
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Last time updated on 20/11/2020