Magnetic Properties of a Quantum Ferrimagnet: NiCu(pba)(D_2O)_3 . 2D_2O

Abstract

We report the results of magnetic measurements on a powder sample of NiCu(pba)(D_2O)_3 \cdot 2D_2O$(pba=1,3-propylenebis(oxamato)) which is one of the prototypical examples of an$S$=1/2 and 1 ferrimagnetic chain. Susceptibility($\chi$) shows a monotonous increase with decreasing temperature (T) and reaches a maximum at about 7 K. In the plot of$\chi T$versus$T$, the experimental data exhibit a broad minimum and are fit to the$\chi T$curve calculated for the ferrimagnetic Heisenberg chain composed of S=1/2 and 1. From this fit, we have evaluated the nearest-neighbor exchange constant$J/k_B=121 K$, the g-values of Ni$^{2+}$and Cu$^{2+}$,$g_{Ni}$=2.22 and$g_{Cu}$=2.09, respectively. Applied external field dependence of$\chi T$ at low temperatures is reproduced fairly well by the calculation for the same ferrimagnetic model.Comment: 7pages, 4 postscript figures, usues REVTEX. appear in J. Phys. Soc. Jpn vol 67 No.7 (1998