We consider an ideal gas of infinitely rigid rods near a perfectly repulsive
wall, and show that the interfacial tension of a surface with rods on one side
is lower when the surface bends towards the rods. Surprisingly we find that
rods on both sides of surfaces also lower the energy when the surface bends. We
compute the partition functions of rods confined to spherical and cylindrical
open shells, and conclude that spherical shells repel rods, whereas cylindrical
shells (for thickness of the shell on the order of the rod-length) attract
them. The role of flexibility is investigated by considering chains composed of
two rigid segments.Comment: 39 pages including figures and tables. 12 eps figures. LaTeX with
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