In this paper a mean-field theory for the spin-liquid paramagnetic
non-superconducting phase of the p- and n-type High-Tc cuprates is
developed. This theory applied to the effective t−t′−t′′−J∗ model with the
{\it ab initio} calculated parameters and with the three-site correlated
hoppings. The static spin-spin and kinematic correlation functions beyond
Hubbard-I approximation are calculated self-consistently. The evolution of the
Fermi surface and band dispersion is obtained for the wide range of doping
concentrations x. For p-type systems the three different types of behavior
are found and the transitions between these types are accompanied by the
changes in the Fermi surface topology. Thus a quantum phase transitions take
place at x=0.15 and at x=0.23. Due to the different Fermi surface topology
we found for n-type cuprates only one quantum critical concentration, x=0.2.
The calculated doping dependence of the nodal Fermi velocity and the effective
mass are in good agreement with the experimental data.Comment: 8 page