We present single contact friction experiments between a glassy polymer and
smooth silica substrates grafted with alkylsilane layers of different coverage
densities and morphologies. This allows us to adjust the polymer/substrate
interaction strength. We find that, when going from weak to strong interaction,
the response of the interfacial junction where shear localizes evolves from
that of a highly viscous threshold fluid to that of a plastically deformed
glassy solid. This we analyse as resulting from an interaction-induced
``interfacial glass transition'' helped by pressure