We study kinetics of diffusion-limited catalytically-activated A+B→B
reactions taking place in three dimensional systems, in which an annihilation
of diffusive A particles by diffusive traps B may happen only if the
encounter of an A with any of the Bs happens within a special catalytic
subvolumen, these subvolumens being immobile and uniformly distributed within
the reaction bath. Suitably extending the classical approach of Wilemski and
Fixman (G. Wilemski and M. Fixman, J. Chem. Phys. \textbf{58}:4009, 1973) to
such three-molecular diffusion-limited reactions, we calculate analytically an
effective reaction constant and show that it comprises several terms associated
with the residence and joint residence times of Brownian paths in finite
domains. The effective reaction constant exhibits a non-trivial dependence on
the reaction radii, the mean density of catalytic subvolumens and particles'
diffusion coefficients. Finally, we discuss the fluctuation-induced kinetic
behavior in such systems.Comment: To appear in J. Chem. Phy