Non-rocky sub-jovian exoplanets in high irradiation environments are rare.
LTT 9979b, also known as TESS Object of Interest (TOI) 193.01, is one of the
few such planets discovered to date, and the first example of an ultra-hot
Neptune. The planet's bulk density indicates that it has a substantial
atmosphere, so to investigate its atmospheric composition and shed further
light on its origin, we obtained {\it Spitzer} IRAC secondary eclipse
observations of LTT 9979b at 3.6 and 4.5 μm. We combined the {\it Spitzer}
observations with a measurement of the secondary eclipse in the {\it TESS}
bandpass. The resulting secondary eclipse spectrum strongly prefers a model
that includes CO absorption over a blackbody spectrum, incidentally making LTT
9979b the first {\it TESS} exoplanet (and the first ultra-hot Neptune) with
evidence of a spectral feature in its atmosphere. We did not find evidence of a
thermal inversion, at odds with expectations based on the atmospheres of
similarly-irradiated hot Jupiters. We also report a nominal dayside brightness
temperature of 2305 ± 141 K (based on the 3.6 μm secondary eclipse
measurement), and we constrained the planet's orbital eccentricity to e<0.01 at the 99.7 \% confidence level. Together with our analysis of LTT
9979b's thermal phase curves reported in a companion paper, our results set the
stage for similar investigations of a larger sample of exoplanets discovered in
the hot Neptune desert, investigations which are key to uncovering the origin
of this population.Comment: 12 pages, 5 figures; accepted to ApJ Letter