Here we report synthesis and characterization of Mg_{1-x}Sc_{x}B_{2}
(0.12T_{c}>6 K.
We find that the Sc doping moves the chemical potential through the 2D/3D
electronic topological transition (ETT) in the sigma band where the ``shape
resonance" of interband pairing occurs. In the 3D regime beyond the ETT we
observe a hardening of the E_{2g} Raman mode with a significant line-width
narrowing due to suppression of the Kohn anomaly over the range 0<q<2k_{F}.Comment: 8 pages, 4 EPS figures, to be published in Phys. Rev.
