Electron energy-loss spectrometry was employed to measure the white lines at
the L23 absorption edges of the 3d transition-metal oxides and lithium
transition-metal oxides. The white-line ratio (L3/L2) was found to increase
between d^0 and d^5 and decrease between d^5 and d^10, consistent with previous
results for the transition metals and their oxides. The intensities of the
white lines, normalized to the post-edge background, are linear for the 3d
transition-metal oxides and lithium transition-metal oxides. An empirical
correlation between normalized white-line intensity and 3d occupancy is
established. It provides a method for measuring changes in the 3d-state
occupancy. As an example, this empirical relationship is used to measure
changes in the transition-metal valences of Li_{1-x}Ni_{0.8}Co_{0.2}O_2 in the
range of 0 < x < 0.64. In these experiments the 3d occupancy of the nickel ion
decreased upon lithium deintercalation, while the cobalt valence remained
constant.Comment: 6 pages, 7 figure
