Observations with the Australia Telescope Compact Array revealed intra-hour variations in the radio source PKS B1322-110 (Bignall et al. 2019). As part of an optical follow-up, we obtained Gemini Hα and Hα continuum (HαC) images of the PKS B1322-110 field. A robust 19 σ detection of PKS B1322- 110 in the Hα−HαC image prompted us to obtain the first optical spectrum of PKS B1322-110. With the Gemini spectrum we determine that PKS B1322-110 is a flat-spectrum radio quasar at a redshift of z = 3.007 ± 0.002. The apparent flux detected in the Hα filter is likely to originate from He ii emission redshifted precisely on the Galactic Hα narrow-band filter. We set upper limits on the emission measure of the Galactic plasma, for various possible cloud geometries
