Growth of high quality, high density single-walled carbon nanotube forests on copper foils

Abstract

We demonstrate the growth of high quality single-walled carbon nanotube (SWCNT) forests on commercial Cu foils by cold-wall chemical vapor deposition. Time-of-flight secondary ion mass spectrometry was employed to study the effect of annealing on the catalyst evolution with or without an AlOₓ barrier layer. X-ray photoelectron spectroscopy was used to investigate the chemical states of the catalyst and the barrier layer. SWCNT forests can be reproducibly grown on Cu foils sputter-coated with Al and Fe layers as thin as 6 nm and 0.4 nm, respectively. Al transforms into AlOₓ on exposure to air and during annealing. Most importantly, such a thin AlOₓ barrier layer ensures not only the growth of SWCNTs but also an Ohmic contact between the as grown SWCNTs and the Cu base as measured by a two-point probe station. The as-grown SWCNTs exhibit a bimodal distribution of diameters ranging from 0.6 to 4.5 nm, with two peaks centered at 0.8 nn and 2.6 nm, respectively.This work supported by Honda Research Institute USA Inc. Sugime H. acknowledges a research fellowship from the Japanese Society for the Promotion of Science (JSPS).This is the author accepted manuscript. The final version is available from Elsevier via http://dx.doi.org/10.1016/j.carbon.2015.11.04