In this paper, the influence of concrete properties such as permeability and environmental conditions (water content) on the spalling behavior of concrete subjected to fire loading is investigated. For this purpose, a special fire-test setup is presented, allowing an improved reproduction of temperature histories observed, e.g., in tunnel fires. Moreover, the developed test setup enables a continuous monitoring of spalling, giving access to the spalling history and the final level of damage of concrete specimens. The obtained results, considering different water/cement-ratios and saturation degrees, are related to the required initial tensile strength determined by means of a numerical assessment tool. Finally, correlations between the identified parameters governing fire-spalling were established and allowed an evaluation of the spalling risk of concrete mixtures. These correlations revealed that β in contrast to requirements given in national and international standards β the combination of water content and permeability may serve as proper key and design parameter, defining the risk of spalling