Unusual emission of visible light is observed in scanning tunneling
microscopy of the quantum well system Na on Cu(111). Photons are emitted at
energies exceeding the energy of the tunneling electrons. Model calculations of
two-electron processes which lead to quantum well transitions reproduce the
experimental fluorescence spectra, the quantum yield, and the power-law
variation of the intensity with the excitation current.Comment: revised version, as published; 4 pages, 3 figure