Some time ago, Fisher and de Gennes pointed out that long-ranged correlations
in a fluid close to its critical point Tc cause distinct forces between
immersed colloidal particles which can even lead to flocculation [C. R. Acad.
Sc. Paris B 287, 207 (1978)]. Here we calculate such forces between pairs of
spherical particles as function of both relevant thermodynamic variables, i.e.,
the reduced temperature t = (T-Tc)/Tc and the field h conjugate to the order
parameter. This provides the basis for specific predictions concerning the
phase behavior of a suspension of colloidal particles in a near-critical
solvent.Comment: 29 pages, 14 figure
