The first angle-resolved photoemission spectroscopy results from MgB2
single crystals are reported. Close to the ΓK and ΓM directions,
three distinct dispersions are observed approaching the Fermi energy, as can be
assigned to the theoretically predicted σ (B 2px,y) and π (B
2pz) bands. In addition, we also observed a small parabolic-like band
centered around Γ, and attributed it to a surface-derived state. Good
agreement between our results and the band calculations suggests that the
electronic structure of MgB2 is of a conventional nature, thus implying that
electron correlations are weak, and may be of little importance to the
superconductivity in this system.Comment: Revtex 3 pages, 3 JPEG figures, submitted to Phys. Rev. Let