What are the mechanisms leading to the shape relaxation of three dimensional
crystallites ? Kinetic Monte Carlo simulations of fcc clusters show that the
usual theories of equilibration, via atomic surface diffusion driven by
curvature, are verified only at high temperatures. Below the roughening
temperature, the relaxation is much slower, kinetics being governed by the
nucleation of a critical germ on a facet. We show that the energy barrier for
this step linearly increases with the size of the crystallite, leading to an
exponential dependence of the relaxation time.Comment: 4 pages, 5 figures. Accepted by Phys Rev Let