Possibilities of straw protection with copper-ethanolamine preparations

Abstract

Slama je stranski proizvod kmetijske dejavnosti in se danes pogosto uporablja kot izolacijski material in strešna kritina v gradbeništvu. Tako kot na les, tudi na slamo vplivajo biotični in abiotični dejavniki, ki povzročajo različne poškodbe. V zadnjem obdobju tako prihaja do pogostejših poškodb slamnatih streh in kritin, zato smo želeli preveriti možnosti za zaščito slame. Ker se danes baker-etanolaminski pripravek Silvanolin uporablja za zaščito lesa pred biotičnimi dejavniki, smo predpostavili, da bi lahko bila to tudi ustrezna zaščita za slamo, ki je ravno tako lignocelulozni material. Slamo smo potapljali v Silvanolin pri različnih koncentracijah (0,25 % in 0,5%) za 2 različno dolgi časovni obdobji (5 min in 60 min). Proučevali smo optimalen čas potapljanja, pri katerem smo dosegli optimalen navzem bakrovih učinkovin. Največji navzem bakra v slamo smo določili pri vzrocih, ki smo jih potapljali v pripravek višje koncentracije in tudi dlje časa. Po drugi strani se je izkazalo, da se baker-etanolaminski pripravki dobro vežejo v slamo. Izpiranje bakra je bilo največje prvi dan, potem pa se je zmanjševalo. Ugotovili smo, da zaščita slame z bakrovimi pripravki zavira rast micelija gliv. Boljšo zaščito predstavlja 0,5 % raztopina, kjer se je ustvarila barierna cona med glivo in slamo.Straw is a by-product of the agricultural industryit is often used as an insulation and roofing material in construction. Like wood, straw is also affected by biotic and abiotic factors causing a variety of damages. Since it lately more often came to degradation of straw roofs, we examined the possibilities of straw protection. Nowadays, copper-ethanolamine preparation is used to protect wood against biological agents, therefore we assumed that this could also be the adequate protection of straw, which is also a lignocellulosic material. The straw was submerged into Silvanolin at different concentrations (0.25 % and 0.5 %) and for 2 different time periods (5 min and 60 min). We studied the optimal impregnation time to reach the optimal absorption of copper substances. The maximum absorption of copper in the straw was determined on samples that have been treated in a solution of a higher concentration, and also for a longer time. On the other hand it has been shown that the copper-ethanolamine preparations form chemical bonds with straw. Leaching of copper was the highest on the first day, but then it decreased. We came to the conclusion that the protection of straw with copper preparations affects the growth of mycelial fungi. The best protection was achieved with 0.5 % concentration of Silvanolin, where a barrier between the fungus and the straw was created

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