A compilation of field surveys on gaseous elemental mercury (GEM) from contrasting environmental settings in Europe, South America, South Africa and China: separating fads from facts
Mercury is transported globally in the atmosphere
mostly in gaseous elemental form (GEM, Hg0
gas),
but still few worldwide studies taking into account
different and contrasted environmental settings are
available in a single publication. This work presents
and discusses data from Argentina, Bolivia, Bosnia
and Herzegovina, Brazil, Chile, China, Croatia, Finland,
Italy, Russia, South Africa, Spain, Slovenia and
Venezuela. We classified the information in four
groups: (1) mining districts where this contaminant
poses or has posed a risk for human populations and/or
ecosystems; (2) cities, where the concentration ofatmospheric mercury could be higher than normal due
to the burning of fossil fuels and industrial activities;
(3) areas with natural emissions from volcanoes; and
(4) pristine areas where no anthropogenic influence
was apparent. All the surveys were performed using
portable LUMEX RA-915 series atomic absorption
spectrometers. The results for cities fall within a low
GEM concentration range that rarely exceeds 30 ng m-3,
that is, 6.6 times lower than the restrictive ATSDR
threshold (200 ng m-3) for chronic exposure to this
pollutant. We also observed this behavior in the former
mercury mining districts, where few data were above
200 ng m-3.We noted that high concentrations of GEM
are localized phenomena that fade away in short
distances. However, this does not imply that they do not
pose a risk for those working in close proximity to the
source. This is the case of the artisanal gold miners that
heat the Au–Hg amalgam to vaporize mercury. In this
respect, while GEM can be truly regarded as a hazard,
because of possible physical–chemical transformations
into other species, it is only under these localized
conditions, implying exposure to high GEM concentrations,
which it becomes a direct risk for humans.Grants
CGL2009-13171 and CTM2012-33918 from the Spanish
Ministry of Economy and Competitiveness and PII1I09-0142-
4389 from theCastilla-LaMancha (Spain)RegionalGovernment.Published713-7346A. Monitoraggio ambientale, sicurezza e territorioJCR Journalrestricte