The Synthesis of Decapyrrylcorannulene And Its Supramolecular Assembly

Abstract

自从富勒烯(又名巴基球)在1985年被发现后,有关富勒烯分子的超分子化学取得了很大的进展。在众多主体分子之中,具有碗状结构的共轭芳香碗烯分子(Corannulene)由于其与富勒烯分子在几何形状、电子性质上的互补受到了科学家的广泛关注。尽管碗烯分子是一种潜在的捕获富勒烯客体的主体分子,但是碗烯(Corannulene)分子本身与富勒烯分子的络合能力十分有限,因此碗烯分子的功能化修饰就显得非常必要。近年来以Corannulene分子为基本骨架,设计合成Corannulene衍生物作为富勒烯的捕获分子成为了该领域的热点。到目前为止,化学家们所合成的Corannulene衍生物对于富勒烯分子的捕获不...Since the fullerenes (also known as backyballs) were discovered in 1985, the supramolecular chemistry of fullerene molecules has made a great progress. Among many main molecules, the conjugated aromatic inclusions (Corannulene) with a bowl-like structure has attracted the interest of scientists, because of their geometrical and electronic complementary properties with fullerene molecules. Althoug...学位:理学硕士院系专业:化学化工学院_无机化学学号:2052014115150

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