We use frequency comb-based optical two-way time-frequency transfer (O-TWTFT)
to measure the optical frequency ratio of state-of-the-art ytterbium and
strontium optical atomic clocks separated by a 1.5 km open-air link. Our
free-space measurement is compared to a simultaneous measurement acquired via a
noise-cancelled fiber link. Despite non-stationary, ps-level time-of-flight
variations in the free-space link, ratio measurements obtained from the two
links, averaged over 30.5 hours across six days, agree to 6×10−19,
showing that O-TWTFT can support free-space atomic clock comparisons below the
10−18 level