Polarization of the cosmic microwave background, though not yet detected,
provides a source of information about cosmological parameters complementary to
temperature fluctuations. This paper provides a complete theoretical treatment
of polarization fluctuations. After a discussion of the physics of
polarization, the Boltzmann equation governing the evolution of the photon
density matrix is derived from quantum theory and applied to microwave
background fluctuations, resulting in a complete set of transport equations for
the Stokes parameters from both scalar and tensor metric perturbations. This
approach is equivalent at lowest order in scattering kinematics to classical
radiative transfer, and provides a general framework for treating the
cosmological evolution of density matrices. The metric perturbations are
treated in the physically appealing longitudinal gauge. Expressions for various
temperature and polarization correlation functions are derived. Detection
prospects and theoretical utility of microwave background polarization are
briefly discussed.Comment: Replaced version corrects factor of 2 error in the Liouville
equation. 24 pages, Postscrip