With this work, we have conducted an extensive search for magnetic fields in
the photosphere of α~And. We have acquired new circular polarisation
spectra with the MuSiCoS and ESPaDOnS sp ectropolarimeters. We have also
obtained FORS1 circular polarisation spectra fro m the ESO Archive, and
considered all previously published magnetic data. This e xtensive dataset has
been used to systematically test for the presence of magnet ic fields in the
photosphere of α~And. We have also examined the high-res olution spectra
for line profile variability. The polarimetric and magnetic data provide no
convincing evidence for photospheric magnetic fields. The highest-S/N phase-
and velocity-resolved Stokes V profiles, obtained with ESPaDOnS, allow us to
place a 3σ upper limit of abou t 100~G on the possible presence of any
undetected pure dipolar, quadrupolar or octupolar surface magnet ic fields (and
just 50~G for fields with significant obliquity). We also conside r and dismiss
the possible existence of more complex fossil and dynamo-generated fields, and
discuss the implications of these results for explaining the non-un iform
surface distribution of Hg. The very high-quality ESPaDOnS spectra have al
lowed us to confidently detect variability of Hg~{\sc ii} λ6149,
\lamb da 5425 and λ5677. The profile variability of the Hg~{\sc ii}
lines is strong, and similar to that of the Hg~{\sc ii} λ3984 line. On
the ot her hand, variability of other lines (e.g. Mn, Fe) is much weaker, and
appears to be attributable to orbital modulation, continuum normalisation
differences and weak, variable fringing