The Southern Marginal Zone of the Limpopo Complex documents strong evidence that CO2-rich (XCO2=0.7–0.9, XH2O= 0.1–0.3) and brine fluids of greatly reduced water activity interacted with cooling metapelitic granulite during the thrust-controlled emplacement at 2.69–2.62 Ga onto the granite-greenstone terrain of the northern Kaapvaal Craton. Interaction of cooling metapelitic granulite with CO2-rich fluids at T 900°C, P > 7.5 kbar. Interaction of hot melt with metapelitic granulite continued until final emplacement in the middle crust (P = 6 kbar, T = 630°C). Brine fluids also initiated shear zone-hosted metasomatism of quartzo-feldspathic gneisses at T between 600 and 900°C and amphibolite-facies lode-gold mineralization. Available data implicate devolatilization of underthrusted greenstone material as the dominant deep crustal source for infiltrating CO2-rich and brine fluids
