Supporting data for publication. Data consists of a range of Electron Microscopy images and current - voltage measurements from fresh and aged organic solar cells. Most of the data was acquired 01/10/2014 - 27/01/15. Device fabrication and measurement was done in the Kroto Research Institute, University of Sheffield. Electron Microscopy was done at the Cavendish Laboratory, University of Cambridge. Further details about the data is included in the Metadata.docx file.This record supports publication available at: https://www.repository.cam.ac.uk/handle/1810/250470This work was supported by the EPSRC [grant number EP/I029257/1]