We report high resolution (R~37,000) integral field spectroscopy of the
central region (r<14arcsec) of the Red Rectangle nebula surrounding HD44179.
The observations focus on the 5800A emission feature, the bluest of the
yellow/red emission bands in the Red Rectangle. We propose that the emission
feature, widely believed to be a molecular emission band, is not a molecular
rotation contour, but a vibrational contour caused by overlapping sequence
bands from a molecule with an extended chromophore. We model the feature as
arising in a Polycyclic Aromatic Hydrocarbon (PAH) with 45-100 carbon atoms.Comment: 13 pages, 9 figures, accepted for publication in ApJ. A version of
the paper with full resolution figures is available at:
http://www.aao.gov.au/local/www/rgs/Sequence-Structure