A series of six-coordinate [Cu(L)L1][BF4]2 (L1 = 2,6-bis{1-oxyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-2-yl}pyridine) complexes are reported. Ferromagnetic coupling between the Cu and L1 ligand spins is enhanced by an L coligand with distal methyl substituents, which is attributed to a sterically induced suppression of its Jahn–Teller distortion

Cespedes, O

Fokin, SV

Greatorex, S

Halcrow, MA

Konno, T

Kulmaczewski, R

Ovcharenko, VI

Sproules, S

Yamada, M

Yoshinari, N

Ferromagnetic coupling between the Cu and L1 ligand radical spins in [Cu(L)L1][BF4]2 (L1 = 2,6-bis{1-oxyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-2-yl}pyridine) is enhanced by a sterically bulky ‘L’ co-ligand

Halcrow, Malcolm A

Greatorex, Sam

Fokin, Sergey V

Kulmaczewski, Rafał

Cespedes, Oscar

Yamada, Mihoko

Yoshinari, Nobuto

Konno, Takumi

Sproules, Stephen

Ovcharenko, Victor I

Research Data Leeds Repository (University of Leeds)

This dataset contains data produced at the University of Leeds: Analytical characterisation of the complexes (CHN microanalysis). Electrospray mass spectra (plotted spectra). X-ray Crystallographic data:  Structure of L3∙5H2O (CCDC 1911909).  Structure of 2∙nMeNO2 (CCDC 1911991). Magnetic susceptibility data (raw and plotted data). Density functional energy minimisation calculations (SPARTAN format).  The density functional exchange constant calculations in the published study associated with this dataset belong to Dr S. Sproules (University of Glasgow).  Ligands referred to in this dataset  Complexes prepared during this study     Molecules calculated in the computational study   

Data to support study of Modulating the Magnetic Properties of Copper(II)/Nitroxyl Heterospin Complexes by Suppression of the Jahn-Teller Distortion

Fokin, Sergey V.

Kulmaczewski, Rafal

Ovcharenko, Victor I.

Halcrow, Malcolm A.

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Modulating the magnetic properties of copper(II)/nitroxyl heterospin complexes by suppression of the Jahn–Teller distortion

White Rose Research Online

Modulating the Magnetic Properties of Copper(II)/Nitroxyl Heterospin Complexes by Suppression of the Jahn–Teller Distortion

https://eprints.whiterose.ac.uk/161623/1/Cu%20PyIMNT%20Inorg%20Chem%20for%20sympleptic.pdf

Modulating the Magnetic Properties of Copper(II)/Nitroxyl Heterospin Complexes by Suppression of the Jahn–Teller Distortion

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Research Data Leeds Repository (University of Leeds)

Enlighten

White Rose Research Online