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Heterogeneous or homogeneous? A case study involving palladium-containing perovskites in the Suzuki reaction
Authors
SP Andrews
SV Ley
+3 more
MD Smith
AF Stepan
H Tanaka
Publication date
1 April 2005
Publisher
'Wiley'
Doi
Cite
Abstract
The utility of a series of palladium-containing perovskite catalysts in the Suzuki reaction is described; turnover numbers of up to 400,000 are reported. A detailed investigation into the mode of action of these catalysts encompassing kinetic studies, catalyst poisoning, microscopy and three-phase tests demonstrate that these heterogeneous materials are pre-catalysts that operate by a solution-phase mechanism. © 2005 Wiley-VCH Verlag GmbH and Co. KGaA
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Last time updated on 18/04/2020
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Oxford University Research Archive
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Last time updated on 30/09/2015