A multi-term theory for solving the Boltzmann equation and a Monte Carlo simulation technique are used to investigate the electron transport in mixtures of molecular nitrogen and oxygen. We investigate the way in which the transport coefficients and spatially resolved transport data are influenced by the amount of O2 in the mixture. This study

was initiated in order to obtain the transport data for input into the fluid models and fluid components of hybrid models of streamers and has resulted in a database of such transport data

Dujko, S. (Sasa)

Ebert, U. (Ute)

Petrović, Z.L. (Zoran)

White, R.D.

English

CWI's Institutional Repository

Publ. Astron. Obs. Belgrade No. 89 (2010), 71-74                                    Contributed Paper 71  ELECTRON TRANSPORT DATA IN N2-O2 STREAMER PLASMA DISCHARGES  SAŠA DUJKO1,2, UTE EBERT2, RONALD WHITE3  and ZORAN Lj. PETROVIĆ1 1Institute of Physics, University of Belgrade, P.O.Box 68,  11080 Zemun Belgrade, Serbia E-mail: sasa.dujko@ipb.ac.rs 2Centre for Mathematics and Informatics (CWI), P.O.Box 94079,  1090 GB Amsterdam, The Netherlands 3ARC Centre for Antimatter-Matter Studies, School of Engineering and Physical Sciences, James Cook University, Townsville 4810, Australia  Abstract. A multi-term theory for solving the Boltzmann equation and a Monte Carlo si-mulation technique are used to investigate the electron transport in mixtures of molecular nitrogen and oxygen. We investigate the way in which the transport coefficients and spa-tially resolved transport data are influenced by the amount of O2 in the mixture. This study was initiated in order to obtain the transport data for input into the fluid models and fluid components of hybrid models of streamers and has resulted in a database of such transport data.      1. INTRODUCTION  Streamers are growing filaments of weakly-ionized non-stationary plasma pro-duced by an ionization front that moves through the non-ionized matter (Ebert et al. 2006). They have applications in diverse areas of science and technology rang-ing from their role in creating the lighting and transient luminous events in the upper atmosphere (Ebert and Sentman 2008) to industrial applications such as those used for the treatment of the polluted gases and water (Grabowski et al. 2005) and those employed for the plasma enhanced vapor deposition in microelec-tronics (Babayan et al. 1998). There have been numerous simulations of streamers (see, e.g. Ebert et al. 2006 and references therein), but the recent 3-dimensional self-consistent hybrid model of Li et al. 2009, is of special interest. In this model, the fast non-equilibrium electrons in the leading part of the ionization front are treated by a Monte Carlo simulation while the low-energy electrons in the rest of the domain are treated using a fluid model. The fluid part is based on the local field approximation and requires the tabulation of electron transport coefficients as a function of the reduced electric field. The fluid model is coupled with the Monte Carlo model via a model interface. To ensure the stable and correct interaction S. DUJKO et al.  72  between these two models, the correct implementation of swarm transport data and accuracy of their calculations are critical steps in modeling. Moreover, in this work we try to show which aspect of kinetic theory developed for swarm physics and which segments of data would be important for further improvement of both fluid and hybrid models of streamers. This is the main avenue we explore in this work.              In this work we solve the Boltzmann equation for electron swarms undergoing ionization and attachment in mixtures of molecular N2 and O2. Values and general trends in the profiles of the mean energy, rate coefficients, drift velocity and diffu-sion tensor are reported here. A Monte Carlo simulation technique is used to cal-culate the spatially resolved transport properties during the development of an electron avalanche and its transition to a streamer.     2. THEORY  The governing equation describing a swarm of charged particles moving through a background of neutral molecules in electric and magnetic fields is given by Boltzmann’s equation for the phase space distribution function ),,( tf cr :                                [ ] ( )fJfmqftf −=∂∂⋅×++∇⋅+∂∂cBcEc .                               (1) Here r and c denote, respectively, the position and velocity of the swarm particle at time t, q and m are the charge and mass of the swarm particle, respectively, while E and B are the electric and magnetic fields. The right hand side of (1) de-notes the linear charged-particle-neutral molecule collision operator, accounting for elastic, inelastic, and non-conservative collisions. The directional dependence of ),,( tf cr  in velocity space is represented by an expansion in terms of spherical harmonics:                                     ( ) ( )∑ ∑∞= −==0][)( )(,,,,lllmlmlm cYtcrftcf?r ,                                   (2)  where )(][ cY lm?  are spherical harmonics and c?  denotes the angles of c. No restric-tions are placed on the number of spherical harmonics nor is any particular form of the time-dependence of the expansion coefficients assumed. The speed depen-dence of the coefficients ( )tcf ,,r  is treated by an expansion about a Maxwellian at an arbitrary time-dependent basis temperature in terms of Sonine polynomials. It is assumed that the hydrodynamic stage has been reached and that spatial de-pendence is treated by the density gradient expansion:                                   ( ) ( ) ( ) ( )∑∞=∇−⊗=0)( ,,,,sss tntftf rccr .                                 (3) Using the above decompositions of f and an implicit finite difference evaluation of time derivatives, the Boltzmann equation is transformed into a hierarchy of doubly infinite coupled inhomogeneous matrix equations for the time-dependent mo-ments. Finite truncation of both the Sonine polynomial and spherical harmonic ELECTRON TRANSPORT DATA IN N2-O2 STREAMER PLASMA DISCHARGES  73  expansions permit solution of this hierarchy by direct numerical inversion. Having obtained the moments, the transport coefficients and other transport properties can be calculated and their explicit expressions are given in our recent publication (Dujko et al. 2010). The reader is referred to a recent Ph.D. thesis (Dujko 2009) for a detailed discussion of a Monte Carlo simulation technique and calculation of the spatially resolved electron transport data under hydrodynamic conditions.   3. RESULTS AND DISCUSSION  We consider the reduced electric field range: 1-1000 Td (1 Td = 10-21 Vm2). The abundance of O2 in the mixture is varied systematically. The preliminary results are obtained for zero gas temperature and thermal effects on transport data will be considered in a future work. The cross sections for the electron scattering in N2 detailed by Stojanović and Petrović 1998, and cross sections for electron scatter-ing in O2 developed by Itikawa et al. 1989, are implemented in this work.  1 10 100 10000.1110 ε   [ eV ]E/n0   [ Td ] 100 - 0 (N2:O2) 80 - 20 (N2:O2) 50 - 50 (N2:O2) 30 - 70 (N2:O2) 0 - 100 (N2:O2) a  0 50 100 150 200 250 300 350-0.20.00.20.40.60.81.01.21.41.6  100 - 0 (N2:O2) 80 - 20 (N2:O2) 50 - 50 (N2:O2) 30 - 70 (N2:O2) 0 - 100 (N2:O2)n 0k eff   [10-15 m3 s-1]E/n0   [ Td ] b  Figure 1: Variation of the mean energy (a) and effective ionization coefficient (b) with E/n0 for various N2-O2 mixtures.  In Fig.1 (a) we show the mean energy as a function of E/n0 for various N2-O2 mixtures. The properties of the cross sections are reflected in the profiles of the mean energy. Fig. 1 (b) displays the variation of the effective ionization coeffi-cient with E/n0 for various N2-O2 mixtures. For clarity, we show the variation of n0keff with E/n0 up to 350 Td. For E/n0 less than ~135 Td and when O2 is present, this transport property is negative, although its value is relatively small. This is a clear sign that the attachment dominates the ionization in this energy region. In the same energy region the flux values are greater than the bulk values of the drift and diffusion (not shown here). However, due to the increasing cross section for ioni-zation and the fact that the cross section for electron attachment becomes negligi-ble at higher energies, the effective ionization coefficient becomes positive. A S. DUJKO et al.  74  very narrow range of E/n0 where the effective ionization coefficient passes through zero is of special interest for modeling of streamers, since it corresponds to the minimal value for the development of an electron avalanche and its transi-tion into a streamer.     In Fig. 2 we show (a) the spatial distribution of an electron swarm and (b) av-erage energy in the direction of electric field for various N2-O2 mixtures. The elec-tron swarm is released at time t = 0, from a single point with a Maxwellian distri-bution of velocities and with a mean starting energy of 25 eV. As can be observed, the spatial profiles of the swarm relax to a Gaussian profile while the average energy has a characteristic slope. Both of these spatial distributions are significant-ly affected by the O2 concentrations.    -0.035 -0.030 -0.025 -0.020 -0.015 -0.010 -0.005-20000020000400006000080000100000120000140000160000180000Number of electronsz   [ m ] 100 - 0 (N2:O2) 80 - 20 (N2:O2) 50 - 50 (N2:O2) 30 - 70 (N2:O2) 0 - 100 (N2:O2)E directiont = 300 ns a 0 20 40 60 80 1007891011121314151617t = 300 nsE direction  100 - 0 (N2:O2) 80 - 20 (N2:O2) 50 - 50 (N2:O2) 30 - 70 (N2:O2) 0 - 100 (N2:O2)Average energy   [ eV ]Number of spatial cells b   Figure 2: The spatial distribution of the electron swarm (a) and average energy (b) in the direction of the electric field for various N2-O2 mixtures for E/n0 of 590 Td.   References  Babayan, S., Jeong, J., Tu, V., Park J., Selwyn G., Hicks, R.: 1998, Plasma Source Sci. Technol., 7, 286 Dujko, S.: 2009, Ph.D. Thesis, James Cook University, Townsville, Australia.  Dujko, S., White R. D., Petrović, Z. Lj., Robson, R. E.: 2010, Phys. Rev. E, 81, 046403. Ebert, U., Sentman, D. D.: 2008, J. Phys. D: Appl. Phys., 41, 230301. Ebert, U., Montijn, C., Briels, T. M. P., Hundsdorfer, W., Meulenbroek B., Rocco A., van Veldhuizen, E. M.: 2006, Plasma Source Sci. Technol., 15, 5118 Grabowski, L. R., van Veldhuizen E. M., Pemen, A. J. M., Rutgers, W. R.: 2005, Plasma Chem. and Plasma Proc., 26, 17. Itikawa, Y., Ichimura, A., Onda, K., Sakimoto, K., Takayanagi, K., Hatano, Y., Hayashi, M., Nishimura, H., Tsurubuchi, S.: 1989, J. Phys. Chem. Ref. Data, 18, 23.  Li, C., Ebert, U., Hundsdorfer, W.: 2009, J. Phys. D: Appl. Phys., 42 202003.      Stojanović, V. D., Petrović, Z. Lj.: 1998, J. Phys. D: Appl. Phys., 31 834.      

Electron transport data in N2-O2 streamer plasma discharges

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