We discuss the composition and size distribution of the dust in the coma of
comet Hale-Bopp. We do this by fitting simultaneously the infrared emission
spectrum measured by the infrared space observatory (ISO) and the measured
degree of linear polarization of scattered light at various phase angles and 12
different wavelengths. The effects of particle shape on the modeled optical
properties of the dust grains are taken into account. We constrain our fit by
forcing the abundances of the major rock forming chemical elements to be solar.
The infrared spectrum at long wavelengths reveals that large grains are needed
in order to fit the spectral slope. The size and shape distribution we employ
allows us to estimate the sizes of the crystalline silicates. The ratios of the
strength of various forsterite features show that the crystalline silicate
grains in Hale-Bopp must be submicron sized. We exclude the presence of large
crystalline silicate grains in the coma. Because of this lack of large
crystalline grains combined with the fact that we do need large amorphous
grains to fit the emission spectrum at long wavelengths, we need only
approximately 4% of crystalline silicates by mass. After correcting for
possible hidden crystalline material included in large amorphous grains, our
best estimate of the total mass fraction of crystalline material is
approximately 7.5%, significantly lower than deduced in previous studies in
which the typical derived crystallinity is 20-30%. The implications of this on
the possible origin and evolution of the comet are discussed. The crystallinity
we observe in Hale-Bopp is consistent with the production of crystalline
silicates in the inner solar system by thermal annealing and subsequent radial
mixing to the comet forming region.Comment: Accepted for publication in Icaru