Crystal Structure of Di-Aqua-Bis-(7-Di-Ehtyl-Amino-3-Formyl-2-Oxo-2H-Chromen-4-Olato-κ(2) O (3), O (4))zinc(II) Dimethyl Sulfoxide Disolvate

Abstract

The structure of the title coordination complex, [Zn(C14H14NO4)2(H2O)2]·2C2H6OS, shows that the ZnII cation adopts an octa­hedral geometry and lies on an inversion center. Two organic ligands occupy the equatorial positions of the coordination sphere, forming a chelate ring motif via the O atom on the formyl group and another O atom of the carbonyl group (a pseudo--diketone motif). Two water mol­ecules occupy the remaining coordination sites of the ZnII cation in the axial positions. The water mol­ecules are each hydrogen bonded to a single dimethyl sulfoxide mol­ecule that has been entrapped in the crystal lattice

    Similar works