We examine the fine structure lines 3P1→3P0 (492 GHz) and
3P2→3P1 (809 GHz) of neutral atomic carbon as bulk molecular
gas mass tracers and find that they can be good and on many occasions better
than 12CO transitions, especially at high redshifts. The notion of CI
emission as an H2 gas mass tracer challenges the long-held view of its
distribution over only a relatively narrow layer in the CII/CI/CO transition
zone in FUV-illuminated molecular clouds. Past observations have indeed
consistently pointed towards a more extended CI distribution but it was only
recently, with the advent of large scale imaging of its 3P1→3P0 transition, that its surprising ubiquity in molecular clouds has
been fully revealed. In the present work we show that under {\it typical} ISM
conditions such an ubiquity is inevitable because of well known dynamic and
non-equilibrium chemistry processes maintaining a significant [C]/[12CO]
abundance throughout Giant Molecular Clouds during their lifetime. These
processes are more intense in star-forming environments where a larger ambient
cosmic ray flux will also play an important role in boosting [C]/[12CO].
The resulting CI lines can be bright and effective H2 mass tracers
especially for diffuse (∼102−103cm−3) gas while in UV-intense
and/or metal-poor environments their H2-tracing capability diminishes
because of large scale CII production but nevertheless remains superior to that
of 12CO. The best place to take full advantage of CI's capacity to trace
H2 is not in the low-z Universe, where large atmospheric absorption at 492
and 809 GHz precludes routine observations, but at high redshifts (\rm z\ga
1).Comment: Accepted for publication at the Monthly Notices of the Royal
Astronomical Society (29 pages, 5 figures