1,4-Dibenzyl-1,4-diazoniabicyclo[2.2.2]octane chlorochromate (DBDABOCC): A mild and selective reagent for efficient oxidation of organic compounds under non-aqueous conditions
863-866The preparation of 1,4-dibenzyl-1,4-diazoniabicyclo[2.2.2]octane
chlorochromate 1 is described. With this reagent benzylic and allylic
alcohols are selectively oxidized to their corresponding carbonyl compounds in excellent
yields. Oximes, thiols and aromatic amines are also converted to their corresponding
carbonyl compounds, disulfides and azo compounds efficiently