1107-1111One new ortho-hydroxy Schiff
base, 2-(N-benzyl-α-iminoethyl)-naphthol (BEIN) in which the hydrogen atom in
the CC(H)=N group is replaced by a methyl substituent, is synthesized. The crystal
structure is determined and ab initio calculations with B3LYP/6-31G**
basis sets are performed. The O ... N distance found in the O-H ... N
hydrogen bond turns out to be quite short and is equal to 2.499 Å. This shortening
is due to the steric repulsion of methyl substituent group and results in strengthening
of the hydrogen bond