We show in this Letter that the spectral details of the FUV radiation fields
have a large impact on the chemistry of protoplanetary disks surrounding T
Tauri stars. We show that the strength of a realistic stellar FUV field is
significantly lower than typically assumed in chemical calculations and that
the radiation field is dominated by strong line emission, most notably Lyman
alpha radiation. The effects of the strong Lyman alpha emission on the chemical
equilibrium in protoplanetary disks has previously been unrecognized. We
discuss the impact of this radiation on molecular observations in the context
of a radiative transfer model that includes both direct attenuation and
scattering. In particular, Lyman alpha radiation will directly dissociate water
vapor and may contribute to the observed enhancements of CN/HCN in disks.Comment: 14 pages, 4 figures, accepted by ApJ Letter