We report new infrared spectroscopic observations of cool DQ white dwarfs by
using Coolspec on the 2.7m Harlan-Smith Telescope. DQs have helium-rich
atmospheres with traces of molecular carbon thought to be the result of
convective dredge-up from their C/O interiors. Recent model calculations
predict that oxygen should also be present in DQ atmospheres in detectable
amounts. Our synthetic spectra calculations for He-rich white dwarfs with
traces of C and O indicate that CO should be easily detected in the cool DQ
atmospheres if present in the expected amounts. Determination of the oxygen
abundance in the atmosphere will reveal the C/O ratio at the core/envelope
boundary, constraining the important and uncertain ^{12}C(alpha,gamma)^{16}O
reaction rate.Comment: 2 pages, 2 figures, to appear in proceedings of the 13th European
Workshop on White Dwarf