Spatially controllable surface chirality at the nanoscale

Abstract

We demonstrate a mechanical approach for manipulating surface chirality at nanoscopic length scales. We use an atomic-force microscope to scribe a step pattern, which is chiral in two dimensions, into a polymer-coated substrate, and control chiral strength by varying the steps’ length-to-width ratio R. We determine the chiral strength by coating the surface with a liquid crystal and measuring its rotation on applying an electric field. The chiral strength vs. R is nonmonotonic: zero for R=1, then reaching a maximum, and tending to zero as R→∞. Our results demonstrate that chiral handedness and strength can be precisely controlled mechanically on nanoscopic length scales

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