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Synthesis Of Fluorinated Metalloporphyrinosilica Imprinted With Templates Through Sol-gel Process
Authors
Biazzotto J.C.
Ciuffi K.J.
+6 more
Iamamoto Y.
Leite C.A.P.
Nascimento O.R.
Sacco H.C.
Serra O.A.
Vidoto E.A.
Publication date
26 November 2015
Publisher
Abstract
We present the synthesis of a hybrid material containing fluorinated iron porphyrins through hydrolysis and polycondensation of iron porphyrin bearing a trifluorosilyl function with tetraethoxysilane in the presence of nitrogen bases acting as template molecules. The presence of metalloporphyrin Soret band is detected in the ultraviolet-visible absorption spectra of all metalloporphyrinosilica-templates. Thermogravimetric analysis and electron paramagnetic resonance of the materials also confirm the presence of metalloporphyrin in a silica network. Electron spectroscopy imaging was that of a non-crystalline microstructure. The iron and silicon distribution are homogeneous for the elements in all particle sites. The iron porphyrinosilicas-template were active as catalysts for cyclooctene epoxidation using iodozylbenzene as oxygen donor. In general, the epoxidation yield is larger for iron porphyrinosilicas-template than for manganese porphyrinosilicas-template. 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