A New Configuration Of The Solid-state Battery: Magnesium|polymer Proton Conductor|gold, Based On The Use Of Poly(o-methoxyaniline)

Abstract

A solid-state battery was constructed by interfacing a pressed pellet of poly(o-methoxyaniline), in the emeraldine form with p-toluene sulfonic acid as doping agent, to a magnesium electrode covered with a film of magnesium perchlorate; the contact on the poly(o-methoxyaniline) was done by means of a gold electrode. The so-obtained cell, Mg|magnesium perchlorate|poly(o-methoxyaniline)|gold, was able to supply energy with a power depending on discharge current and on environmental humidity. Values of power up to 2.5 mW cm-2 at discharge currents of about 2 mA cm-2 were reached. © 1997 Elsevier Science S.A.9013136Gemeay, A.H., Nishiyama, H., Kuwabata, S., Yoneyama, H., (1995) J. Electrochem. Soc., 142, p. 4190Momma, T., Kakuda, S., Yarimizu, H., Osaka, T., (1995) J. Electrochem. Soc., 142, p. 1766Tsutsumi, H., Fukuzawa, S., Ishikawa, M., Morita, M., Matsuda, Y., (1995) J. Electrochem. Soc., 142, pp. L168Morita, M., Miyazaki, S., Ishikawa, M., Matsuda, Y., Tajima, H., Adachi, K., Anan, F., (1995) J. Power Sources, 54, p. 214Barbero, C., Miras, M.C., Schnyder, B., Haas, O., Kotz, R., (1994) J. Mater. Chem., 4, p. 1775Gauthier, M., Belanger, A., Bouchard, P., Kapfer, B., Ricard, S., Vassort, G., Armand, M., Krause, L., (1995) J. Power Sources, 54, p. 163Scrosati, B., Neat, R.J., (1993) Application of Electroactive Polymers, p. 182. , B. Scrosati (ed.), Chapman and Hall, LondonBoinowitz, T., Suden, G.T., Tormin, U., Krohn, H., Beck, F., (1995) J. Power Sources, 56, p. 179Capuano, F., Casalbore-Miceli, G., Giro, G., Scrosati, B., (1994) J. Appl. Electochem., 24, p. 114Camaioni, N., Casalbore-Miceli, G., Martelli, A., Yang, M.J., (1997) J. Appl. Electrochem., 27Kumar, G., Sivashanmugam, A., Muniyandi, N., Dhawan, S.K., Trivedi, D.C., (1996) Synth. Met., 80, p. 279Gazotti W.A., Jr., De Paoli, M.-A., Synth. Met., , in pressPourbaix, M., (1966) Atlas of Electrochemical Equilibria in Aqueous Solutions, p. 101. , Pergamon Press, Oxfor