Novel C-h Activation In A Bis-tetrairidium Carbonyl Complex Of The Sandwich Compound [fe(η5-c5h5)(η5-p 3c2but 2)]: Crystal And Molecular Structures Of [ir4(co)11{fe(η5-c5h 5)(η5-p3c2bu(t) 2)}]
The syntheses and structural determinations of novel complexes of the type [Ir4(CO)11L] {L = [Fe(η5-P3C2But 2)(η5s-P2C3But 3)] or [Fe(η5-C5H5)(η5-P 3C2But 2)]} and [HIr4(CO)10-(μ-Fe(η5-C5H 5)(η5-P3CH2(CMe 2)CBut)}Ir4(CO)11], involving an unusual C-H activation, are described.3441443Bartsch, R., Hitchcock, P.B., Nixon, J.F., (1987) J. Chem. Soc., Chem. Commun., p. 1146Binger, P., Glaser, G., (1994) J. Organomet. Chem., 479, pp. C28Bartsch, R., Hitchcock, P.B., Nixon, J.F., (1988) J. Organomet. Chem., 340, pp. C37Müller, C., Bartsch, R., Fischer, A., Jones, P.G., (1993) J. Organomet. Chem., 453, pp. C16Nixon, J.F., (1988) Chem. Rev., 88, p. 1327Nixon, J.F., (1991) Endeavour, 15, p. 49(1993) Chem. Ind., p. 404Bartsch, R., Gelessus, A., Hitchcock, P.B., Nixon, J.F., (1992) J. Organomet. Chem., 430, pp. C10Müller, C., Bartsch, R., Fischer, A., Jones, P.G., (1993) Polyhedron, 12, p. 1383Chini, P., Ciani, G., Garlaschelli, L., Manassero, M., Martinengo, S., Sironi, A., Canziani, F., (1978) J. Organomet. Chem., 152, pp. C35Besançon, K., Laurenczy, G., Lumini, T., Roulet, R., Gervasio, G., (1993) Helv. Chim. Acta, 76, p. 2926. , and references thereinMann, B.E., Vargas, M.D., Katthar, R., (1992) J. Chem. Soc., Dalton Trans., p. 1725Mann, B.E., Pickup, B.T., Smith, A.K., (1989) J. Chem. Soc., Dalton Trans., p. 889Churchill, M.R., Hutchinson, J.P., (1978) Inorg. Chem., 17, p. 3528Della Pergola, R., Garlaschelli, L., Martinengo, S., Demartin, F., Manassero, M., Sansoni, M., (1987) Gazz. Chim. Ital., 117, p. 245Shapley, J.R., Stuntz, G.F., Churchill, M.R., Hutchinson, J.P., (1979) J.Chem. Soc., Chem. Commun., p. 219Vargas, M.D., Pereira, R.M.S., Braga, D., Grepioni, F., (1993) J. Chem. Soc., Chem. Commun., p. 1008Nicholls, J.N., Raithby, P.R., Vargas, M.D., (1986) J. Chem. Soc., Chem. Commun., p. 1617Demartin, F., Manassero, M., Sansoni, M., Garlaschelli, L., Raimondi, C., Martinengo, S., Canziani, F., (1981) J. Chem. Soc., Chem. Commun., p. 52
