A new class of catalysts having a metal/metal oxide core surrounded by a few nitrogen-enriched graphene layers (NGR) has recently brought immense attention in research. Until now, NGR catalysts have mostly been employed for hydrogenation reactions. In this work, we expand the field of applicability of NGR catalysts to cyclopropanation reactions. The activity of Fe2O3/NGr@C has been studied by using ethyl diazoacetate and \u3b1-methylstyrene as substrates. Various parameters such as solvents, temperature and time were changed. Fe2O3/NGr@C-catalysts showed best activity in dimethoxyethane at 60 oC, affording high yields of the desired cyclopropanes (mixture of cis and trans isomers) and only 1-2 % of ethyl maleate and fumarate (Figure 1). The catalyst gradually deactivates after each recycle, but we were able to reactivate the recovered catalyst by treating it with dilute H2O2 (1:10 with distilled water). Like \u3b1-methylstyrene, several olefins such as 4-chloro-\u3b1-methyl styrene, 4-methylstyrene, 2- methylstyrene, 3-methylstyrene, 4-chlorostyrene, 4-t-butylstyrene, 1-octene etc. have been tested in order to explore the substrate scope. The corresponding cyclopropanes were obtained in high to excellent isolated yields (84-98%). In all cases trans diastereoselectivity was found, but even the minor cis isomer could be isolated in a pure form
