One of the least understood properties of comets is the compositional
structure of their nuclei, which can either be homogeneous or heterogeneous.
The nucleus structure can be conveniently studied at millimeter wavelengths,
using velocity-resolved spectral time series of the emission lines, obtained
simultaneously for multiple molecules as the body rotates. Using this
technique, we investigated the sources of CH3OH and HCN in comet 103P/Hartley
2, the target of NASA's EPOXI mission, which had an exceptionally favorable
apparition in late 2010. Our monitoring with the IRAM 30 m telescope shows
short-term variability of the spectral lines caused by nucleus rotation. The
varying production rates generate changes in brightness by a factor of 4 for
HCN and by a factor of 2 for CH3OH, and they are remarkably well correlated in
time. With the addition of the velocity information from the line profiles, we
identify the main sources of outgassing: two jets, oppositely directed in a
radial sense, and icy grains, injected into the coma primarily through one of
the jets. The mixing ratio of CH3OH and HCN is dramatically different in the
two jets, which evidently shows large-scale chemical heterogeneity of the
nucleus. We propose a network of identities linking the two jets with
morphological features reported elsewhere, and postulate that the chemical
heterogeneity may result from thermal evolution. The model-dependent average
production rates are 3.5x10**26 molec/s for CH3OH and 1.25x10**25 molec/s for
HCN, and their ratio of 28 is rather high but not abnormal. The rotational
temperature from CH3OH varied strongly, presumably due to nucleus rotation,
with the average value being 47 K.Comment: Published in ApJ 756, 80 (2012). Supplementary materials available at
http://www.its.caltech.edu/~mdrahus/103p_paperII.htm
