Degradation of phenol using US/periodate/nZVI system from aqueous solutions

Abstract

In the present work, the degradation of phenol from aqueous solutions was investigated using periodate/zero valent iron nanoparticle (nZVI) in the presence of ultrasound at a batch reactor. The Experimental tests were carried out using pre-designated concentrations of nZVI, periodate, and pH ranging from 1-7 mM, 0.5-5 mM, 3-11 respectively. During the all experimental tests the ultrasonic reactor was operated at a fix frequency (40 kHz), temperature (33±1) and power (350 W). The results of nZVI/periodate/ultrasound system on degradation of phenol showed that the removal efficiency was indeed affected by the amount of free radicals produced to initiate the oxidative decomposition of phenol. also, by increasing the nZVI loading to 3 mM and periodate concentration to 3 mM, the efficiency of phenol removal was increased. Besides, the acidic pH (pH = 3) was found to be more effective than neutral and alkaline pH in degradation of phenol. © 2019 Global NEST Printed in Greece. All rights reserved