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Electrochemical reduction of 1-phosphinyl-2-sulfonylethylenes and the ESR spectra of their anion radicals
Authors
Berdnikov E.
Il'yasov A.
+4 more
Mukhitova F.
Tantasheva R.
Vafina A.
Zaripova R.
Publication date
1 March 2020
Publisher
Abstract
1. In aprotic and limitedly protogenic media, electrochemical reduction takes place with the cleavage of the C-S bond (EEC mechanism) and in protogenic media with the hydrogenation of the C=C bond (ECE mechanism). 2. The SO2 group does not prevent the distribution of the spin density over the whole molecule. © 1981 Plenum Publishing Corporation
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Last time updated on 04/04/2020