CORE
🇺🇦
make metadata, not war
Services
Services overview
Explore all CORE services
Access to raw data
API
Dataset
FastSync
Content discovery
Recommender
Discovery
OAI identifiers
OAI Resolver
Managing content
Dashboard
Bespoke contracts
Consultancy services
Support us
Support us
Membership
Sponsorship
Community governance
Advisory Board
Board of supporters
Research network
About
About us
Our mission
Team
Blog
FAQs
Contact us
Ene reaction of 4-phenyl-3H-1,2,4-triazole-3,5(4H)-dione with dicyclopentadiene
Authors
Kiselev V.
Konovalov A.
+3 more
Kornilov D.
Lekomtseva I.
Reshetnikova O.
Publication date
1 March 2020
Publisher
Abstract
© 2015 Pleiades Publishing, Ltd. The kinetics of the ene reaction of endo-dicyclopentadiene with 4-phenyl-3H-1,2,4-triazole-3,5(4H)-dione in benzene, toluene, acetonitrile, 1,2-dichloroetane, and chloroform have been studied. The reaction volumes and enthalpies have been determined, and the activation volume in toluene has been calculated from the pressure kinetic data. The "anomalous" ratio ΔVcorr≠/ΔVr = 1.34 corresponds to a concerted cyclic transition state, though the addition product has acyclic structure
Similar works
Full text
Available Versions
National Open Repository Aggregator (NORA)
See this paper in CORE
Go to the repository landing page
Download from data provider
oai:rour.neicon.ru:rour/178104
Last time updated on 04/04/2020